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Product NO : TII-1

3D Raman Microscopy System, Micro-Nano Scale Micro spectroscopy Nanofinder®30

UV system for strained Si measurements

Stress measurement of Si device

Local stress on the surface of a Si device can be evaluated by analyzing the shift of the Si Raman peak. For this measurement Nanofinder®30 UV model was developed. The UV model combines both: high spatial and spectral resolution.

Echelle grating feature

To obtain high spectral resolution (0.5 cm-1) and high throughput (30%) the 52 cm focal length spectrometer was designed to adopt an Echelle grating. To get the same spectral resolution with standard spectrometer it is necessary to use much larger device (1.3 m focal length).

Si stress measurement resolution

With 52 cm spectrometer, equipped with an Echelle grating it is possible to measure:
Strain of 0.05 % <0.5 cm-1 @364 nm (hardware resolution)
Strain of 0.01 % <0.1 cm-1 (spectral line fitting software).

Non-destructive analysis

Using resonance excitation a low laser power is sufficient to acquire Raman spectra with narrow bandwidth (no sample heating) and good S/N ratio.

Si Raman peak at 520 cm-1
Minimum distortion of data.
Sample: monocrystalline Si
Laser wavelength: 364 nm
Exposure: 1 sec

Laser power: 0.4 mW
Si stress distribution image
Area: 5.5 × 5.5 μm,
Laser power: 0.4 mW
Mapping step: 100 nm (55×55 points)
Exposure: 0.1 sec/point,
Total measurement time: 5min.

Ar-ion excitation laser at 364 nm line

With the 364 nm excitation wavelength the penetration depth inside Si wafer is only 4 nm: an extremely thin surface layer can be measured. Confocal optics and optics inside spectrometer are optimized for UV excitation. Optimized optics for UV-VIS excitation is also available.

Highest spatial resolution

With UV excitation wavelength and optimized confocal optics lateral resolution of 130 nm (as shown in the figure below) is possible.
Step response in lateral direction of < 130 nm
Step response = distance, when signal increased from 10% to 90% from maximum value.
Excitation laser wavelength 364 nm, objective lens 100 × Immersion, N.A.1.2

Sample data

SiO2/Si Raman spectrum and Raman image



Cross-hatch pattern of strained SiGe film grown on Si substrate.
Image is obtained with Raman shift function.
Raman shift between the darkest "A" and the brightest "B" spots of the image is 0.4 cm-1 only.
Measurement conditions:
Laser wavelength: 365 nm
Objective lens: 10×, N.A.0.95
Grating: 75 G/mm (Echelle)
Laser power: 1.5 mW
Raman spectrum at points "A" and "B".

Combination of Echelle grating (hardware) and spectral line fitting (software) provides the unique ability for high quality fine Raman shift (sample strain) imaging.
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